High-yield, regiospecific bis-functionalization of C₇₀ using a Diels-Alder reaction in molten anthracene.
نویسندگان
چکیده
A regiospecific bis-adduct of C70 with anthracene was prepared with unusually high yield (68%) by the Diels-Alder reaction in the absence of solvent (melt). The structure of the bis-adduct was an unexpected 12 o'clock isomer, as determined by single crystal X-ray diffraction, thermal gravimetric analysis (TGA) and spectroscopy.
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ورودعنوان ژورنال:
- Chemical communications
دوره 50 73 شماره
صفحات -
تاریخ انتشار 2014